6. Paramore

Paramore shot their 'MTV Unplugged’ performance in late summer 2009 in New York City. Vocalist Hayley Williams, guitarists Josh Farro and Taylor York, drummer Zac Farro and bassist Jeremy Davis took to the stage armed with only acoustic guitars and a handful of songs designed to shock your heart into life. Although only a very lucky few were there to watch them tear through hits "That's What You Get," "Misery Business" and "Decode," as well as "Ignorance" and "Brick By Boring Brick" off of their latest album, Brand New Eyes, MTV.com has the entire performance here for everyone else to see. It is in the live setting where Paramore shine and their Unplugged performance proves that yet again.